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1-Di­methyl­amino-3-di­methyl­iminio-1-(p-methyl­phenyl)­prop-1-ene perchlorate

✍ Scribed by Girija, C. R. ;Begum, Noor Shahina ;Sridhar, M. A. ;Lokanath, N. K. ;Prasad, J. S.


Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
273 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis


Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.007 A Ê R factor = 0.075 wR factor = 0.272 Data-to-parameter ratio = 14.7

For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.


📜 SIMILAR VOLUMES


1-Di­methyl­amino-3-di­methyl­iminio-1-(
✍ Girija, C. R. ;Begum, Noor Shahina ;Sridhar, M. A. ;Lokanath, N. K. ;Prasad, J. 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 275 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.050 wR factor = 0.148 Data-to-parameter ratio = 12.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.057 wR factor = 0.204 Data-to-parameter ratio = 14.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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The ortho-disubstituted aromatic ring in the title compound, C 27 H 32 N 2 , is twisted by 76.1 (1) with respect to the isopropylsubstituted ring and by 89.3 (1) with respect to the methylsubstituted ring. The amino N atom is linked intramolecularly to the imino N by a hydrogen bond [NÁ Á ÁN = 2.686

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The molecule of the title compound, C 20 H 10 N 2 , displays no imposed symmetry, but is largely planar [one phenyl ring is twisted by 10.4 (1) out of the plane of the rest of the molecule]. The central C C bond length is 1.371 (3) A Ê . The molecules are linked by a weak hydrogen bond of the form C