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1-Butyl-3-methylimidazolium p-toluenesulfinate: a novel reagent for synthesis of sulfones and β-ketosulfones in ionic liquid

✍ Scribed by Anil Kumar; Manoj Kumar Muthyala


Book ID
113929859
Publisher
Elsevier Science
Year
2011
Tongue
French
Weight
284 KB
Volume
52
Category
Article
ISSN
0040-4039

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Alkenes undergo smooth cyclopropanation with ethyl diazoacetate using a catalytic amount of rhodium acetate dimer, Rh 2 (OAc) 4 , immobilized in the air-and moisture-stable 1-butyl-3-methylimidazolium hexafluorophosphate ionic liquid, [bmim]PF 6 , to afford cyclopropanecarboxylates in excellent yiel