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1-(3-Chloro­benzo­yl)-3-methyl-3-phenyl­thio­urea

✍ Scribed by Khawar Rauf, M. ;Badshah, Amin ;Bolte, Michael ;Ahmad, Imtiaz

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
133 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, C~15~H~13~ClN~2~OS, the geometric parameters do not show unusual features. There are three molecules in the asymmetric unit. The molecules are linked by N—H...S hydrogen bonds to form dimers.

📜 SIMILAR VOLUMES

1-(3-Chloro­benzo­yl)-3-[3-(trifluoro­me
1-(3-Chloro­benzo­yl)-3-[3-(trifluoro­methyl)phenyl]thio­urea
✍ Khawar Rauf, M. ;Badshah, Amin ;Flörke, Ulrich 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 174 KB

## Single -crystal X-ray study T = 120 K Mean (C-C) = 0.004 A R factor = 0.057 wR factor = 0.120 Data-to-parameter ratio = 16.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

1-(2-Chloro­benzo­yl)-3-phenyl­thio­urea
1-(2-Chloro­benzo­yl)-3-phenyl­thio­urea
✍ Khawar Rauf, M. ;Badshah, Amin ;Saeed, Aamer ;Bolte, Michael 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 107 KB

The phenyl and benzoyl groups in the title molecule, C~14~H~11~ClN~2~OS, are __cis__ and __trans__, respectively, with respect to the C=S bond. The molecular conformation is stabilized by an N—H...O hydrogen bond and the crystal packing is characterized by N—H...O and N—H...S hydrogen bonds.

1-(2-Chloro­benzo­yl)-3-(3-chloro­phen­y
1-(2-Chloro­benzo­yl)-3-(3-chloro­phen­yl)thio­urea
✍ Khawar Rauf, M. ;Badshah, Amin ;Bolte, Michael 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 191 KB

In the title compound, C 14 H 10 Cl 2 N 2 OS, the geometric parameters do not show unusual features. The thiocarbonyl and carbonyl groups are almost coplanar with the chlorophenyl ring, as reflected by the torsion angles of 0.7 (3) and À5.8 (3) , respectively. The structure exhibits inter-and intram

1-(4-Chloro­phen­yl)-3-(4-methyl­benzo­y
1-(4-Chloro­phen­yl)-3-(4-methyl­benzo­yl)thio­urea
✍ Saeed, Aamer ;Flörke, Ulrich 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 182 KB

In the structure of the title compound, C~15~H~13~ClN~2~OS, the dihedral angle between the two aromatic ring planes is 30.46 (8)°. Intermolecular N—H...S hydrogen bonds link the molecules into dimeric units which are stacked along [010].

1-(3-Methyl­benzo­yl)-3-(2-methyl­phen­y
1-(3-Methyl­benzo­yl)-3-(2-methyl­phen­yl)thio­urea
✍ Saeed, Aamer ;Flörke, Ulrich 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 200 KB

In the structure of the title compound, C~16~H~16~N~2~OS, the dihedral angle between the two aromatic ring planes is 68.08 (9)°. Intermolecular N—H...S hydrogen bonds link the molecules into dimeric units which are stacked along [100].