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(ω-2,ω-2,ω-3,ω-3)-Tetradeuterio-fatty acids for mechanistic studies of enzyme-catalyzed hydroxylation reactions

✍ Scribed by John H. Horner; Martin Newcomb

Book ID
115558909
Publisher
John Wiley and Sons
Year
2012
Tongue
French
Weight
181 KB
Volume
55
Category
Article
ISSN
0022-2135

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1-Hydroperoxy-2-oxabicyclo[n.4.0]alkanes (n=3, 4, 5 and 10) on heating with formic or acetic acid containing a catalytic amount of sulfuric acid undergo a rearrangement into lactones of v-acyloxy-(v-3)-hydroxyalkanoic acids by a mechanism related to the Criegee reaction.