σ-Bond Metathesis of Alkanes on a Silica
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Christophe Copéret; Olivier Maury; Jean Thivolle-Cazat; Jean-Marie Basset
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Article
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2001
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John Wiley and Sons
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English
⚖ 119 KB
C-C activation of unactivated alkanes on a silica-supported neopentyl neopentylidene Ta complex [Eq. (1)] affords the alkane cross-metathesis products tBuCH R and an alkane-metathesis catalyst. Since the activity and product distributions are similar to those obtained with a silica-supported Ta hydr