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ππ*Transition of ethylene: electron correlation and Rydberg character

✍ Scribed by B. Levy; J. Ridard

Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
407 KB
Volume
15
Category
Article
ISSN
0009-2614

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✦ Synopsis

The excircd singlet (n r;*) state of planar ethylene is calculated in ;I CT0 basis set by a second-order perturbation method. It is shown that the transition energy is nearly independent of the Rydberg character of the x* orbital and therefore electron correlation is introdnced.

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