μ-Peroxo-bis[acetonitrilebis(ethylenediamine)cobalt(III)] tetratriflate
✍ Scribed by McMullen, Sarah E. ;Hagen, Karl S.
- Book ID
- 104479176
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 500 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
Single-crystal X-ray study T = 100 K Mean '(C±C) = 0.004 A Ê R factor = 0.040 wR factor = 0.100 Data-to-parameter ratio = 13.3
For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
## Abstract Oxygenation of solutions containing bis(ethylenediamine) cobalt(II) ions leads to a mixture of diastereomeric forms of μ‐peroxo‐μ‐hydroxo‐bis[bis(ethylenediamine) cobalt(III)] cations. The existence of a meso‐isomer has now been proved by its isolation as perchlorate and by an X‐ray str
Dedicated to Prof. Dr. Siluio Fullub on the occasion of his 60th birthday (23.1X.85) The reaction of the meso-diol, A,A-[(en),Rh(OH)2Rh(en)2]4+, with aqueous H,O, and 1 equiv. of NaOH at YO" forms the pperoxo-p-hydroxo-bridged species ~l,A-[(en),Rh(O,,OH)Rh(en)~]~+ in a yield of cu. 50%. The compoun