μ-Oxo diferric complexes as oxidation catalysts with hydrogen peroxide and their potential in asymmetric oxidation
✍ Scribed by Carole Duboc-Toia; Stéphane Ménage; Claude Lambeaux; Marc Fontecave
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 212 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Non-heme diiron complexes, as models of methane monooxygenase, provide a new class of catalysts for oxidation reactions, We show here that such complexes have the potential t'or catalyzing stereoselective oxidations of sulfides by hydrogen peroxide.
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A great variety of olefinic substrates having aromatic, carbocyclic and aliphatic olefins are effectively and selectively oxidized with oxygen-rich molybdenum(VI) complexes, namely 5 and [PPh 4 ][Mo(O) 3 -(QO)] 6 (QOH = 8-quinolinol) as catalyst, NaHCO 3 as co-catalyst and H 2 O 2 as the terminal o