𝔖 Bobbio Scriptorium
✦   LIBER   ✦

μ-Oxo diferric complexes as oxidation catalysts with hydrogen peroxide and their potential in asymmetric oxidation

✍ Scribed by Carole Duboc-Toia; Stéphane Ménage; Claude Lambeaux; Marc Fontecave


Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
212 KB
Volume
38
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis


Non-heme diiron complexes, as models of methane monooxygenase, provide a new class of catalysts for oxidation reactions, We show here that such complexes have the potential t'or catalyzing stereoselective oxidations of sulfides by hydrogen peroxide.


📜 SIMILAR VOLUMES


Unmatched efficiency and selectivity in
✍ Swarup K. Maiti; Subhajit Dinda; Ramgopal Bhattacharyya 📂 Article 📅 2008 🏛 Elsevier Science 🌐 French ⚖ 198 KB

A great variety of olefinic substrates having aromatic, carbocyclic and aliphatic olefins are effectively and selectively oxidized with oxygen-rich molybdenum(VI) complexes, namely 5 and [PPh 4 ][Mo(O) 3 -(QO)] 6 (QOH = 8-quinolinol) as catalyst, NaHCO 3 as co-catalyst and H 2 O 2 as the terminal o