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μ-Glycine-κ2O:O′-di-μ-sulfido-bis[(glycinato-κ2N,O)oxidomolybdenum(V)]

✍ Scribed by Li, Ya Min ;Li, Yong Hong ;Zhai, Cui Ping

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 850 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807054761

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✦ Synopsis

In the title compound, [Mo 2 (C 2 H 4 NO 2 ) 2 O 2 S 2 (C 2 H 5 NO 2 )], the two Mo V atoms are bridged by two 2 -S atoms and one glycine ligand in an O:O 0 -bidentate mode. In addition, each Mo V atom is bonded to one terminal oxygen ligand and chelated by one N,O-bidentate glycinate ligand, resulting in a distorted octahedral coordination. A complex hydrogen-bonding network is constructed by intermolecular N-HÁ Á ÁO hydrogen bonds.

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