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(η6-Benzene)dichloro[tris(2-isopropylphenyl) phosphite]ruthenium(II) dichloromethane solvate

✍ Scribed by Meijboom, Reinout ;Muller, Alfred ;Roodt, Andreas

Publisher: International Union of Crystallography
Year: 2006
Tongue: English
Weight: 182 KB
Volume: 62
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536806025256

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✦ Synopsis

In the title compound, [RuCl 2 (C 27 H 33 O 3 P)(C 6 H 6 )]ÁCH 2 Cl 2 , the Ru-P bond distance is 2.2790 (4) A ˚, and the Ru-Cl bond distances are 2.4052 (4) and 2.4046 (4) A ˚. The title compound is the first reported structure containing tris(2isopropylphenyl)phosphite as a ligand. The effective cone angle ( E ) for the tris(2-isopropylphenyl) phosphite was calculated to be 160 .

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✍ Kan, Jian ;Zhang, Li-Yi ;Gao, Li-Bin ;Shi, Lin-Xi ;Chen, Zhong-Ning 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 222 KB

(η6-Benzene)dichloro­[tris­(2-isopropyl­phen­yl) phosphite]­ruthenium(II) dichloro­methane solvate

✦ Synopsis

(η6-Benzene)dichloro[tris(2-isopropylphenyl) phosphite]ruthenium(II) dichloromethane solvate