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(η6-Arene)ruthenium oxomolybdenum and oxotungsten clusters. Stereochemical non-rigidity of [{Ru(η6-p-MeC6H4Pri)}4Mo4O16] and crystal structure of [{Ru(η6-p-MeC6H4Pri)}4W2O10]

✍ Scribed by Artero, Vincent; Proust, Anna; Herson, Patrick; Thouvenot, René; Gouzerh, Pierre


Book ID
120650558
Publisher
Royal Society of Chemistry
Year
2000
Tongue
English
Weight
433 KB
Volume
10
Category
Article
ISSN
1359-7345

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✍ Danielle Laurencin; Eva Garcia Fidalgo; Richard Villanneau; Françoise Villain; P 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 265 KB

## Abstract Reactions of the molybdates Na~2~MoO~4~⋅2 H~2~O and (__n__Bu~4~N)~2~[Mo~2~O~7~] with [{Ru(arene)Cl~2~}~2~] (arene=C~6~H~5~CH~3~, 1,3,5‐C~6~H~3~(CH~3~)~3~, 1,2,4,5‐C~6~H~2~(CH~3~)~4~) in water or organic solvents led to formation of the triple‐cubane organometallic oxides [{Ru(η^6^‐arene