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(η3-Allyl)[(S)-(+)-(2-pyrrolidinyl­methyl)­pyrrolidine]­palladium(II) trifluoro­methane­sulfonate

✍ Scribed by Jones, Matthew D. ;Almeida Paz, Filipe A. ;Davies, John E. ;Johnson, Brian F. G.

Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
360 KB
Volume
59
Category
Article
ISSN
1600-5368

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✍ Silvia Schaffner; Ludwig Macko; Markus Neubufger; Margareta Zehnder 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 German ⚖ 510 KB

1 9.VIII.96) Crystal and solution structures of the enantiomerically pure and the racemic pairs of (q3-allyl) { 2-[2'-(diphenylphosphino)phenyl]-4,5-dihydro-4-phenyloxazole}palladium(II) hexafluorophosphates (1, and rac-1, resp.) and tetraphenylborates (2, and ruc-2, resp.) as well as (q3-ally1){2-[

Synthesis, Structure, and 2D-NMR Studies
Synthesis, Structure, and 2D-NMR Studies of Novel Chiral (η3-Allyl)palladium(II) Complexes Containing the Bidentate Ligand Sparteine
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Novel cationic allylpalladium(II) complexes containing the alkaloid (-)-sparteine (1) as a bidentate ligand have been prepared. Two of them, [q3-(cyclohex-2-enyl)] (sparteine)palladium(II) hexafluorophosphate ([Pd(v3-C6H,)(sparteine)][PF6]; 3b) and (sparteine)[~3-(1,1,3-triphenylallyl)]palladium(II)

Synthesis, and Solution and Solid-State
Synthesis, and Solution and Solid-State Structures of (η3-Allyl){(4S)-4-benzyl-2-[2′-(diphenylphosphino)phenyl]- 4,5-dihydrooxazole-P,N}palladium(II) Hexafluorophosphates. Comparison with Dichloro{(4S)-2-[2′-(diphenylphosphino)phenyl]-4,5-dihydro-4-phenyloxazole-P,N}zinc(II)
✍ Natalie Baltzer; Ludwig Macko; Silvia Schaffner; Margareta Zehnder 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 German ⚖ 574 KB

## Abstract Crystal and solution structures of the [Pd^II^(η^3^‐allyl)] and of the [Pd^II^(η^3^‐1,3‐diphenylallyl)] complexes, 4 and 5, respectively, with (4__S__)‐4‐benzyl‐2‐[2′‐(diphenylphosphino)phenyl]‐4,5‐dihydrooxazole (3) were determined by X‐ray crystallography and 2D‐NMR spectroscopy. Comp