Synthesis and Reactivity of the First η6
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Marjolaine Doux; Louis Ricard; François Mathey; Pascal Le Floch; Nicolas Mézaill
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Article
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2003
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John Wiley and Sons
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English
⚖ 219 KB
👁 1 views
## Abstract It has been shown that 2 equiv. of 2,3,5,6‐tetraphenylphosphinine (**2**) react with [Rh(COD)~2~][BF~4~] to yield the bis(η^1^‐phosphinine)Rh^I^ complex **6**, whose X‐ray crystal structure is presented. On the other hand, 2,6‐bis(trimethylsilyl)phosphinines **4** and **5** react with R