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η 6 -Hexahelicene Complexes of Iridium and Ruthenium: Running along the Helix

✍ Scribed by Álvarez, Celedonio M.; Barbero, Héctor; García-Escudero, Luis A.; Martín-Alvarez, Jose M.; Martínez-Pérez, Cristina; Miguel, Daniel


Book ID
111917271
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
570 KB
Volume
51
Category
Article
ISSN
0020-1669

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Synthesis and Reactivity of the First η6
✍ Marjolaine Doux; Louis Ricard; François Mathey; Pascal Le Floch; Nicolas Mézaill 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 219 KB 👁 1 views

## Abstract It has been shown that 2 equiv. of 2,3,5,6‐tetraphenylphosphinine (**2**) react with [Rh(COD)~2~][BF~4~] to yield the bis(η^1^‐phosphinine)Rh^I^ complex **6**, whose X‐ray crystal structure is presented. On the other hand, 2,6‐bis(trimethylsilyl)phosphinines **4** and **5** react with R