Disposable medical supplies are currently made of polypropylene, which are conveniently sterilized by exposure to g-rays. However, the homopolymers (HP) and random copolymer (CP) of polypropylene, when exposed to high-energy g-irradiation, undergo oxidative degradation and loss in mechanical propert
γ-ray-induced degradation in ethylene–propylene copolymer
✍ Scribed by Harish B. Thorat; C. S. Prabhu; Suresh Kumar K.; M. V. Pandya
- Publisher
- John Wiley and Sons
- Year
- 1996
- Tongue
- English
- Weight
- 341 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0021-8995
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✦ Synopsis
The stabilization of polypropylene-disposable medical syringes against the y-ray-induced degradation has been the subject of active research during the last decade due to the largescale use of y-irradiation for sterilization purposes. Ethylene-propylene (EP) copolymers have been suggested as suitable alternatives to polypropylene for these purposes. In this article, we investigated the effect of irradiation dose and postirradiation time on the melt index and mechanical properties of an EP copolymer. We also determined the chemical changes occurring during irradiation and storage using IR spectroscopy and have made an attempt to co-relate the changes in chemical structure to the changes in mechanical properties and melt index measurements.
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## Abstract The purpose of the present work is to investigate the compositional difference of polypropylene–polyethylene block copolymers (PP‐__b__‐PE) manufactured industrially by the process of degradation and hydrogenation, respectively. Each of the PP‐__b__‐PE copolymers was fractionated into t