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β-substituted pyrroles via electrophilic substitution of n-triisopropylsilylpyrrole.

✍ Scribed by Joseph M Muchowski; Dennis R Solas

Book ID
104219982
Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
137 KB
Volume
24
Category
Article
ISSN
0040-4039

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Pyrrolobenzoxazepine ring construction through metalation and electrophilic substitution of N-(2-hydroxymethylphenyl)pyrrole
✍ Manfred Schlooser; Ferenc Faigl 📂 Article 📅 1994 🏛 Elsevier Science 🌐 French ⚖ 440 KB

N-(2-Hydroxymethylphenyl)pyrrole was found to be amenable to selective a-metalation. Trapping with a variety of electrophilic reagents afforded the expected products with moderate to high yields. Derivatives formed by treatment of the organometahic intermediate with aldehydes, ketones or carbon diox