𝔖 Bobbio Scriptorium
✦   LIBER   ✦

β-Oxy-α-diazo carbonyl compounds. III. Rh2(AcO)4 mediated decomposition of β-acetoxy-α-diazo esters. Application to the synthesis of natural 3-deoxy-2-keto aldonic acids (KDO and DAH)

✍ Scribed by Fidel J. López-Herrera; Francisco Sarabia-García

Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
322 KB
Volume
35
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

p-Acemxy-a4iaz.o esters yield a-en01 amate esters quantitatively by reaction with dirhodittm temmtate. The reaction was used to prepare tJte major natural cmtpounds 3-Deoxy-D-arabiio-2-Heptulosonic lrcid (DAH, 1) aud 3-Deoxy-D-manno-2-Cktulo.wnic

📜 SIMILAR VOLUMES

β-Oxy-α-diazo-carbonyl compounds. Part 5
β-Oxy-α-diazo-carbonyl compounds. Part 5: An improved synthesis of β-hydroxy-α-diazo esters derived from monosaccharides and synthetic applications in the chemistry of 3-deoxy-2-ulosonic acids
✍ Francisco Sarabia; Fidel Jorge López-Herrera 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 79 KB

Reactions of ethyl 2-diazoacetate with aldehydo sugars and monosaccharide derivatives in their hemiacetal form are reported. The use of diethyl zinc led to an improvement of yields and shorter reaction times compared with neutral conditions as previously described. The resulting products represent p

ChemInform Abstract: β-Oxy-α-diazo-carbo
ChemInform Abstract: β-Oxy-α-diazo-carbonyl Compounds. Part 6. Synthesis and Reactivity of 3-Deoxy-2-diazo-esters Derived from Monosaccharides. Applications in the Synthesis of 2-C-Alkyl-KDO Analogues and Related Compounds.
✍ Francisco Sarabia; Fidel Jorge Lopez-Herrera 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 40 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v