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β-Fragmentation of alkoxy radicals. An approach to the synthesis of ring a of vernolepin

✍ Scribed by C.G Francisco; R Freire; M.S Rodríguez; E Suárez

Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
242 KB
Volume
28
Category
Article
ISSN
0040-4039

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Fragmentation of alkoxy radicals: Mechan
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✍ R Hernández; J.J Marrero; E Suárez; A Perales 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 278 KB

## The formation of the B-peroxylactone (4) &ring the photolysis of lactol (3) .oo ## with (diace@yiodo)-benzene (DIB) and iodine under oxygen atmosphere a!emostrates the presence of a peroxyradical intermediate in the tandem p-fragmentation-intramolecularfunctionalization reaction. We have rec