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β-Donor Bonds in Compounds Containing SiON Fragments

✍ Scribed by Dr. Norbert W. Mitzel; Dipl.-Chem. Udo Losehand

Publisher: John Wiley and Sons
Year: 1997
Tongue: English
Weight: 356 KB
Volume: 36
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.199728071

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The compounds Cl 2 Si(ONMe 2 ) 2 and Cl 2 Ge(ONMe 2 ) 2 were by the small angles SiON [102.8(1) and 103.7(1)°] and GeON [102.0(1)°], and the distances Si•••N (2.438 and 2.450 A ˚) and prepared by the reaction of the appropriate tetrachlorides with N,N-dimethylhydroxylamine in the presence of 2,6-Ge•