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β-d-glucosyl-hydroxymethyluracil: A novel modified base present in the DNA of the parasitic protozoan T. brucei

✍ Scribed by Janet H. Gommers-Ampt; Fred Van Leeuwen; Antonius L.J. de Beer; Johannes F.G. Vliegenthart; Miral Dizdaroglu; Jeffrey A. Kowalak; Pamela F. Crain; Piet Borst

Book ID
119064377
Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
1001 KB
Volume
75
Category
Article
ISSN
0092-8674

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Synthesis of Oligodeoxynucleotides Containing 5-(β-D-Glucopyranosyloxymethyl)-2′-deoxyuridine, a Modified Nucleoside in the DNA of Trypanosoma Brucei
✍ Martin de Kort; Edwin Ebrahimi; Eric R. Wijsman; Gijs A. van der Marel; Jacques H. 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 257 KB 👁 1 views

The synthesis of the recently discovered modified DNA base derivative 20, readily available from thymidine in 48%, afforded the fully protected nucleoside 22 in 96% yield. The 5-(β-D-glucopyranosyloxymethyl)-2Ј-deoxyuridine (β-dJ, 1) is described. TMSOTf mediated β-glucosylation of latter compound w