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β-Cleavage of Bis(homoallylic) Potassium Alkoxides. Preparation of 3-Hydroxypropyl and 4-Hydroxybutyl Propenyl Ketones from γ- and δ-Lactones. Synthesis of (±)-Rose oxide

✍ Scribed by Roger L. Snowden; Simon M. Linder; Bernard L. Muller; Karl H. Schulte-Elte


Publisher
John Wiley and Sons
Year
1987
Tongue
German
Weight
450 KB
Volume
70
Category
Article
ISSN
0018-019X

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✦ Synopsis


Products isolated by column chromatography on silica gel (cf: Euper. PurtJ ; compositions of tautomeric mixturcs measured at 25"; in CDCI, solution, by 'H-NMR (360 MHL) spectroscopy. b, Yield from y-butyrolactone (1). ') Yicld from 6-valerolactone (2). *) Yicld from 3-methyl-6-valerolactone (3).