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β-Arylthio-α-chloroalkyl Ethers — Novel 1,1-Bis-electrophiles for Geminal Alkylation.

✍ Scribed by Alexey V. Gromov; William A. Smit


Book ID
101986062
Publisher
John Wiley and Sons
Year
2006
Weight
24 KB
Volume
37
Category
Article
ISSN
0931-7597

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## Abstract 1‐[(5‐Amino‐1‐methyl‐1__H__‐1,2,4‐triazol‐4‐ylium)(alkyl/aryl)‐methyl]pyridinium dichlorides 3a–h [geminal bis(heteroarylium) salts] were synthesized in high yield from 5‐amino‐1‐methyl‐1__H__‐1,2,4‐triazole (6a) and the 1‐[(alkyl/aryl)chloromethyl]pyridinium chlorides 1a–h under mild,