α-Nitrosocyclohexanecarboxylic acid as a possible intermediate in the nitrosodecarboxylation of cyclohexanecarboxylic acid
✍ Scribed by E. F. J. Duynstee; Miss M. E. A. H. Mevis
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 198 KB
- Volume
- 85
- Category
- Article
- ISSN
- 0165-0513
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📜 SIMILAR VOLUMES
N-Acylimines are of current interest and have been isolated or proposed as intermediates in various reactions 192 ; elimination reactions of a-substituted amides to form N-acylimines have been reported2. During the course of studies on a-substituted a-amino acids, we have observed reactions that are
Key Wool Index-
a-Methylbenzylamides, useful intermediates in the resolution of carboxylic acids, are cleaved with a two step procedure; enolizable amides are not racemized. The usefulness of diastereomericct-methylbenzylamides in the resolution of racemic carboxylit acids has been amply dem0nstrated.l We have foun