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α-Nitro Ketone Synthesis Using N-Acylbenzotriazoles.

✍ Scribed by Alan R. Katritzky; Ashraf A. A. Abdel-Fattah; Anna V. Gromova; Rachel Witek; Peter J. Steel


Book ID
101987016
Publisher
John Wiley and Sons
Year
2006
Weight
28 KB
Volume
37
Category
Article
ISSN
0931-7597

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The reduction of 2-nitrocyclohexanones to the 2-nitrocyclohexanols with sodium borohydride followed by treatment of the ,9-nitroalcohols with sodium hydride and subsequent acidification of the salts leads to the regioselective synthesis of conjugated nitrocyclohexenes from cyclohexanones. The resurg