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α-( N -Carbamoyl)alkylcuprate Chemistry in the Synthesis of Nitrogen Heterocycles

✍ Scribed by Dieter, R. Karl; Lu, Kai

Book ID
127150269
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
143 KB
Volume
67
Category
Article
ISSN
0022-3263

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📜 SIMILAR VOLUMES

ChemInform Abstract: α-(N-Carbamoyl)alky
ChemInform Abstract: α-(N-Carbamoyl)alkylcuprate Chemistry in the Synthesis of Nitrogen Heterocycles.
✍ R. Karl Dieter; Kai Lu 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 38 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Synthesis of (±)-isoretronecanol, (±)-cu
Synthesis of (±)-isoretronecanol, (±)-curassanecine, (±)-heliotridane, (±)-tashiromine and (±)-5-epitashiromine via α-(N-carbamoyl)alkylcuprate chemistry
✍ R.Karl Dieter; Rhett Watson 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 113 KB

Vinylation of N-Boc-2-pyrrolidinylcuprate reagents with functionalized vinyl iodides followed by N-Boc deprotection and cyclization affords 1-methylidine pyrrolizidine and indolizidine carbon skeletons. Functional group manipulation of the exo-cyclic olefin provides direct synthetic entries to the p