α Mechanical relaxation in poly(vinyl chloride): effect of ageing and crosslinking
✍ Scribed by R Flores; J Perez; P Cassagnau; A Michel; J.Y Cavaillé
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 650 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0032-3861
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In this work we investigate by means of dielectric relaxation spectroscopy how segmental motions occurring in poly(vinyl chloride) (PVC) are modified by blending of PVC with small amounts of two different homopolymers: crystalline poly(⑀-caprolactone) (PCL) and glassy syndiotactic poly(methylmethacr
Semiinterpenetrating polymer networks (SIPNs) of PVC/isocyanate/polytriol were prepared by premixing small (150 m dia.) porous (30% voids) unplasticized PVC particles, 10% by weight of isocyanate, and a triol at different OH/NCO mol ratios. Three types of isocyanates (methylene bis-phenyl diisocyana