α-Iminocarboxamide Nickel Complexes: Synthesis and Uses in Ethylene Polymerization
✍ Scribed by Rojas, Rene S.; Wasilke, Julia-Christina; Wu, Guang; Ziller, Joseph W.; Bazan, Guillermo C.
- Book ID
- 120156365
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 202 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0276-7333
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📜 SIMILAR VOLUMES
2-Diphenylphosphanyl-and 2-alkylphenylphosphanyl-4-hindered or retarded. The reactivity of 1d remains high towards nickel salts in polar solvents, but in contrast to 1a-c, methylphenols 1 or their silyl ethers 2 and equimolar amounts of nickelocene react in benzene preferably to give yielding 4, a s
## Abstract The oxidative addition of benzyl chloride to Ni(cod)~2~ in the presence of 1,4‐bis(2,6‐diisopropylphenyl)acenaphthenediimine followed by chloride abstraction affords [(__η__^3^‐CH~2~C~6~H~5~)Ni(__α__‐diimine)][PF~6~] (__α__‐diimine = 1,4‐bis(2,6‐diisopropylphenyl)acenaphthenediimine) in