α-imino carbenium ions: Is the α-imino group really destabilizing?

Destabilized carbenium ions: α-imidoyl c

Destabilized carbenium ions: α-imidoyl carbenium ions and the electron impact mass spectra of α-haloaldimines and α-haloketimines

✍ Thomas Sürig; Hans-Friedrich Grützmacher; Norbert de Kimpe 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 639 KB

## Abstract A series of α‐chloro‐ and α‐bromoketimines compounds (1‐9) with different substituents at the α‐position and at the imino group has been investigated by electron impact mass spectrometry as possible precursors of the correspondingly substituted α‐imidoyl carbenium ion, an important clas