𝔖 Bobbio Scriptorium
✦   LIBER   ✦

α-Ethoxycarbonyl and α-methoxy substituted radical clocks

✍ Scribed by Martin Newcomb; Michelle A. Filipkowski; Cathy C. Johnson


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
249 KB
Volume
36
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


A theoretical study of α-substituted cyc
✍ M. H. Lien; A. C. Hopkinson 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 692 KB

The structures of a-X-cyclopropyl and a-X-isopropyl radicals (X = H, CH3, NH2, OH, F, CN, and NC) are reported at the RHF 3-21G level of theory. The isopropyl radicals are pyramidal with out-of-plane angles varying from 12" (X = CN) to 39" (X = NH2), and barriers to inversion ranging from 0.4 kcal/m