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α-Deuterium kinetic isotope effects in reactions of methyllithium: is better aggregation the cause of lower reactivity?

✍ Scribed by Torkil Holm


Book ID
103232970
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
336 KB
Volume
506
Category
Article
ISSN
0022-328X

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A very high S-deuterium kinetic isotope effect, k(CH3)/k(CD3) =2.l3 at ~o'c, was found for the solvolysis of 2-(3'-chlorophenyl)-l,l,l-trifluoro-2propyl tosylate(&) and the a-CD3 analogue