✍ Scribed by Alan R. Katritzky; Jie Chen; Sergei A. Belyakov
No coin nor oath required. For personal study only.
Stable, crystalline a-(benzotriazolyl)methyl phenyl thioethers (1), easily wepared from carbonyl compounds, thiophenol and benzotriazole, are convenient reagents for the phenylthiomethylatlon of trimethylsilyl cyanide, trimethylaUylsilane, and lrimethylsilyl enol ethers to afford the conesponding substituted thioethers and [5-phenylthioalkylketones (3) in good yields.
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## Abstract The α‐chloronitroso compounds **1a–1f** were made to react with methyl and phenyl Grignard reagents. N‐methyl and N‐phenyl substituted ketonitrones **2** and **3** were obtained in 48‐78% yield. The structure of these labile nitrones is based on their spectroscopic properties and on the
Contains A Database Of Approximately 70,000 Reactions And 4000 Of The Most Frequently Consulted Reagents. Fully Searchable By Structure And Sub-structure, Reagent, Reaction Type, Experimental Conditions, And Keyword. Also Includes A Searchable Interface: Acronym Finder (an Interface For Scientific A