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α-Alkyl-α-aminosilanes. 2. A2H NMR study of organolithium stabilization by silicon and by phenyl in solution

✍ Scribed by Scott McN. Sieburth; Joseph J. Somers


Book ID
103405243
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
369 KB
Volume
52
Category
Article
ISSN
0040-4020

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The formation of the a-substituted radicals 1-9 with the 4pyridyl (?), l-naphthyl(8), and the 2-naphthyl(9) substituent by thermolysis of their dimers 1-3 in solution was investigated. The activation parameters of the homolysis of the central CC bond were obtained from kinetic measurements of the th