Überraschende Bildung von 5-Hexen-1-ol bei der Wittig-Reaktion von 4-(2-Tetrahydropyranyloxy)-2-butanon mit Triphenylphosphinmethylen

✍ Scribed by Janistyn, Boris ;Hänsel, Wolfram

• Publisher: Wiley (John Wiley & Sons)
• Year: 1975
• Tongue: English
• Weight: 172 KB
• Volume: 108
• Category: Article
• ISSN: 0009-2940
• DOI: 10.1002/cber.19751080408

✦ Synopsis

Surprising Formation of 5-Hexen-1-01 by the Wittig Reaction of 4-(2-Tetrahydropyranyloxy)-2butanon with Triphenylphosphinemethylene

We report the formation of 5-hexen-1-01 (3) by a Wittig Reaction depending of the experimental conditions. The structure of the unexpected product was elucidated mainly by H-n.m.r.-spectroscopy.