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Über Steroide. (21. Mitteilung). α,β-ungesättigte Aldehyde der Pregnenreihe

✍ Scribed by K. Miescher; A. Wettstein; C. Scholz


Publisher
John Wiley and Sons
Year
1939
Tongue
German
Weight
852 KB
Volume
22
Category
Article
ISSN
0018-019X

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## Abstract Reduction of the 11‐keto to the 11β‐hydroxyl group in the 16α‐methylated allopregnanes II and VIIIb has been accomplished. In the case of the 20‐enol acetate II, sodium borohydride was used, whereas in the case of the 11,20‐diketone VIIIb, prepared in a conventional manner from II, sele