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Über Reaktionen oxygenierter Kobalt(II)-Chelate. VI. Präparative Darstellung von diastereoisomeren Tetrakis(äthylendiamin)-μ-peroxo-μ-hydroxodikobalt(III)-perchloraten

✍ Scribed by Margareta Zehnder; Silvio Fallab

Publisher: John Wiley and Sons
Year: 1975
Tongue: German
Weight: 772 KB
Volume: 58
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19750580812

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✦ Synopsis

On Reaction8 of oxygenated Cobalt(I1) Chelates. Vk. Preparation of diastereoisomeric tetrakis( ethylenediamine) -pperoxo -p hydroxodicobalt(II1) Perchlorates , Summary. Oxygenation of Co(cn)$+ leads to a mixture of two isomcric forms of [(en)aCo(Os, 02.1)-Co(en)g] (ClO& * 1190 from which the less soluble meso form can bc readily crystallized. Further *) Der Brllckenring ist in diesem Fall nahezu planar [6].

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