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Über eine Additionsverbindung zwischen Oxalylchlorid und Dioxan

✍ Scribed by Varvoglis, Georg An.


Publisher
Wiley (John Wiley & Sons)
Year
1938
Weight
212 KB
Volume
71
Category
Article
ISSN
0365-9631

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An Unexpected Reaction between Oxalyl Chloride and Atropisomeric Diamines Chiral diamines like (__S__)‐1,1′‐binaphthalene‐2,2′‐diamine (3a) were acylated by oxalyl chloride to yield mainly a macrocyclic lactame 5, whereas the eight‐membered oxamide 4 was formed only in small quantity.