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Über die Schwefelnitride (SN)2und (SN)x

✍ Scribed by Margot Goehring; Dietrich Voigt

Publisher
Springer
Year
1953
Tongue
English
Weight
134 KB
Volume
40
Category
Article
ISSN
0028-1042

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Thermally generated stannylenes R2Sn insert efficiently into Sn-X bonds (X = Cl, Br, SPh) as well as into electron deficient Sn-Sn bonds e.g. in Me2(Hal)Sn-Sn(Hal)Me2, but not into hexaalkyldistannanes R6Sn2 under the same conditions; stannylenes R2Sn always behave as nucleophiles here. During our s