Über die katalysierte Flüssigphasenoxidation normalkettiger Alk-1-ene

✍ Scribed by U. Barth; H. Fiedler; G. Gross; Frau G. Lauterbach; Dr. D. Schnurpfeil

• Publisher: John Wiley and Sons
• Year: 1981
• Tongue: English
• Weight: 864 KB
• Volume: 323
• Category: Article
• ISSN: 1615-4150
• DOI: 10.1002/prac.19813230606

✦ Synopsis

The Catalyzed Liquid‐Phase Oxidation of Normal Alk‐1‐enes

The efficiencies of various homogeneous soluble transition metal compounds to increase epoxide yields in the autoxidation of alk‐1‐enes were studied. Combinations of typical autoxidation and typical epoxidation catalysts were also used. It was proved through balance experiments, that in no case yields of 50% or more of the corresponding epoxides were obtained. The simple mechanism (epoxidation via allylic hydroperoxides) assumed only insufficiently reflects the reaction course.