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Über die Eigenschaften einiger wasserlöslicher Azo-Initiatoren

✍ Scribed by Nuyken, Oskar ;Kerber, Robert

Publisher
Wiley (John Wiley & Sons)
Year
1978
Weight
503 KB
Volume
179
Category
Article
ISSN
0025-116X

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✦ Synopsis

Abstract

Water soluble azo compounds of the structure 1a, b, 2a, b, 3, 4, and 5 decompose, depending on the substitution of the aromatic ring, in water already at room temperature. Therefore, they are useful initiators for solution and emulsion polymerisations in this temperature region. Reactions competing with thermolysis, as the formation of a hydrazone (pH>8) and ionic reactions with suitable reagents (phenols) are described.

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