Über En-Synthesen mit Singulett-Sauersto
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K. H. Schulte-Elte; G. Ohloff
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Article
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1968
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John Wiley and Sons
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German
The dye-sensitized photooxygenation leads in the case of (-)-caryophyllene (1) to 4 allylhydroperoxides, and with (-)-iso-caryophyllene (2) additionally to 2 tertiary compounds of this kind. Thestereochemistry of the isolated 6 caryophylladienols derivatives 6-11 is e1ucidated.R~ that way an interpr