Nach den Versuchen von HORECKER ;1? bilden bei dec K4LD 2, zwei Lysinrestr pro Molekel mit Dihydroxyaceton-phosphat eine SCHIFF'sChe Rase, die durch Keduktion rnit Natriumborhydrid zum entsprechenden Clycerinderivat stabilisiert werden kann. Kiirzlich haben MORSE und Mitarb. [Z] gezeigt, dass LALD e
Über die Aldolase der Kaninchenleber: Molekulargewicht, Dissoziation in Untereinheiten. Über Aldolasen, 5. Mitteilung
✍ Scribed by Ph. Christen; H. Göschke; F. Leuthardt; A. Schmid
- Publisher
- John Wiley and Sons
- Year
- 1965
- Tongue
- German
- Weight
- 496 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Pentacyclic chromium complexes are produced from the bisazo dyestuffs 1,2- (resp. 3)-(2-amino-benzenesulfonamido)-ethane (resp. propane) + B-naphtol. It is concluded from their absorption spectra that their steric arrangement corresponds to a ~1:Z-sandwich complex)) linked internally, preference being given to one of the possible coordination arrangements. Because of the great similarity of their spectra to that of a previously described (( 1 : 2-chromium-sandwich complex)) from anthranilic acid +@-naphthol, it is concluded that they are arranged in the same way as the latter.
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