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Études Conformationnelles II. Intensités Intégrées des Bandes ν(OH) Libre Pour Quelques Cyclohexanols Secondaires et Tertiaires Stéréoisomères

✍ Scribed by G. Chiurdoglu; W. Masschelein


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
343 KB
Volume
68
Category
Article
ISSN
0037-9646

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✦ Synopsis


Abstract

Integrated intensities of OH stretching absorption bands have been determined for a series of substituted cyclohexanols. The measurements, reported for 16 alcohols, do not indicate any significant intensity difference between axial and equatorial hydroxyl groups. There appears to be a small but significant difference between the intensity of secondary and tertiary alcohols. No appreciable polar effects on the OH linkage due to alkyl group substituents on carbon atoms other than C~1~, appear to exist.