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Étude de composés d'addition des acides de LEWIS XVII. Synthèse cétonique de Friedel & CRAFTS en présence de chlorure d'aluminium radioactif marqué par 36Cl1)

✍ Scribed by G. Oulevey; B.-P. Susz


Publisher
John Wiley and Sons
Year
1961
Tongue
German
Weight
324 KB
Volume
44
Category
Article
ISSN
0018-019X

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✦ Synopsis


Benzoyl chloride and AlC1~3~ give an addition compound with a dative oxygenaluminium bond. The FRIEDEL‐CRAFTS synthesis of benzophenone from benzoyl chloride and benzene in the presence of Al^36^C1~3~ is shown by the authors to give rise to a statistical repartition of the radioactive chlorine between the HC1 evolved and the addition compound of benzophenone and AlCl~3~.