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Äthinierungsreaktionen, XXIII. Reaktionen am 11H-Dibenzo[c.f][1.2]diazepinon-(11)

✍ Scribed by Ried, Walter ;Piesch, Steffen


Book ID
101813379
Publisher
Wiley (John Wiley & Sons)
Year
1966
Tongue
English
Weight
339 KB
Volume
99
Category
Article
ISSN
0009-2940

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Simple and general synthesis of new 11H-
✍ Graziano Baccolini; Carla Boga; Giulia Guizzardi; Stefano Ponzano 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 183 KB

Treatment at room temperature of benzothiadiphosphole 1 with bis-Grignard 2 gives intermediate A, which after 3 h gives intermediate A%. Subsequent addition of RMgX or sodium alcoholate and final treatment with S 8 and water affords the title compounds 5 in good yields. From the reaction mixture it