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Zwitterionic (E)-2-hydr­oxy-6-[(o-tolyl­iminio)meth­yl]phenolate 0.07-hydrate

✍ Scribed by Temel, Ersin ;Albayrak, Çiĝdem ;Büyükgüngör, Orhan ;Odabaşoğlu, Mustafa


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
262 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis


Zwitterionic (E)-2-hydroxy-6-[(o-tolyliminio)methyl]phenolate 0.07-hydrate Ersin Temel, a C ¸ig ˆdem Albayrak, b Orhan Bu ¨yu ¨kgu ¨ngo ¨ra and Mustafa Odabas ¸og ˘lu b *


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The title compound, C~15~H~15~NO~3~, derived from the condensation of dehydroacetic acid and __p__-toluidine, crystallizes in a zwitterionic form with cationic iminium and anionic enolate groups, which complete a six-membered pseudocycle __via__ an intramolecular N—H...O hydrogen bond. C—H...O inter