Zwitterionic 1-phosphonioalkyl dithiophosphinates
✍ Scribed by Florian Breitsameter; Hans-Peter Schrödel; Alfred Schmidpeter
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 153 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1042-7163
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✦ Synopsis
The title compounds (and, in part, their seleno analogs) result from the oxidation of an ylidylphosphine and also from the addition of ylides to a perthiophosphonic anhydride. They can be deprotonated and alkylated to give anions or cations, respectively. The reaction with phenacyl bromide opens a
📜 SIMILAR VOLUMES
More than a dozen stationary points on the potential energy surface for the 1 : 1 glycine zwitterion-water complex have been investigated at Hartree-Fock or MP2 levels of theory with basis sets ranging from split valence (4-31G) to split valence plus polarization and diffuse function (6-31 + + G\*\*
The zwitterion, 1 -[ 4-[ (4-hydroxy -1 -naphthyl)thio]butyl]quinuclidinium hydroxide inner salt, was synthesized from tetrahydro-l-(4-hydroxy-l-naphthyl)thiophenium hydrochloride and quinuclidine and characterized by NMR and IR spectroscopy. Polymerization of the zwitterion was studied over the temp
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