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Zur stereoselektiven Synthese von 2-O-Benzyl-1-O-hexadecyl-sn-glycerol

✍ Scribed by Bauer, Friederike ;Rueß, Klaus-Peter ;Liefländer, Manfred

Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
419 KB
Volume
1992
Category
Article
ISSN
0947-3440

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✦ Synopsis

Stereoselective Synthesis of 2‐O‐Benzyl‐1‐O‐hexadecyl‐sn‐glycerol

Due to the versatility of 2‐O‐benzyl‐1‐O‐hexadecyl‐sn‐glycerol (7) as building block for various alkyl ether lipids and alkyl ether lyso‐lipids, 7 was prepared from D‐mannit following two different strategies. The final product 7 was obtained either via the intermediate 1,2‐O‐isopropylidene‐sn‐glycerol (1) or via 3,4‐O‐isopropylidene‐D‐mannit (8) in an overall yield of 6% or 11%, respectively.

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