𝔖 Bobbio Scriptorium
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Zur näheren Kenntnis des 1-Camphenylsystems - 1-Camphenylverbindungen des Lithiums, Zinns und Quecksilbers

✍ Scribed by Dr. D. Schenke; Prof. Dr. K.-H. Thiele

Book ID
105353710
Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
451 KB
Volume
332
Category
Article
ISSN
1615-4150

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✦ Synopsis

About the 1‐Camphenyl System – 1‐Camphenyl Compounds of Lithium, Tin and Mercury

1‐Camphenyl lithium, 1‐camphenyl isobutyl mercury an 1‐camphenyl triethyl tin were synthesized and characterized by their ^13^C n.m.r. spectra. The lithium compound contains σ,η^1^‐bonded allyl groups and suggests a weak interaction between the exocyclic double bonds and the metal atoms. The coupling constants ^1^J(^199^Hg‐^13^C) and ^1^J(^119^Sn–^13^C) in the spectra of the mercury and the tin compound allow to compare the donor strength of 1‐camphenyl anion with those of other carbanions.

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