Zur Molekülverknüpfung mit Schwefelchloriden. IX. Reaktion von Schwefeldichlorid mit N-Allyl-anilinen. Eine Synthese für 2-Chlormethyl-2,3-dihydro-1,4-benzothiazine

✍ Scribed by Prof. Dr. M. Mühlstädt; Dr. K. Hollmann; Dr. M. Möder

• Book ID: 105353776
• Publisher: John Wiley and Sons
• Year: 1990
• Tongue: English
• Weight: 486 KB
• Volume: 332
• Category: Article
• ISSN: 1615-4150
• DOI: 10.1002/prac.19903320610

✦ Synopsis

Molecule Linkage by Sulfur Chlorides. IX. The Addition Reaction of Sulfur Dichlorides with N‐Allyl‐anilines. A Synthesis for 2‐Chloromethyl‐2,3‐dihydrobenzo‐1,4‐thiazines

Reactions of different substituted N‐allyl‐anilines 1 with sulfur dichloride yield 2‐chloromethyl‐2,3‐dihydrobenzo‐1,4‐thiazines 3a–i. The identification of the products was carried out by mass spectroscopy and ^1^H‐n.m.r.‐spectroscopy. The seven‐membered cyclic isomers of the S, N‐heterocycles 3, dihydro‐benzo‐1,5‐thiazepanes 5 were not obtained.