Zur Kristallstruktur von Li3InCl6

✍ Scribed by Michael O. Schmidt; Mathias S. Wickleder; Gerd Meyer

• Publisher: John Wiley and Sons
• Year: 1999
• Tongue: German
• Weight: 69 KB
• Volume: 625
• Category: Article
• ISSN: 0372-7874
• DOI: 10.1002/(sici)1521-3749(199904)625:4<539::aid-zaac539>3.0.co;2-j

✦ Synopsis

Colorless single crystals of Li 3 InCl 6 are obtained from a 3 : 1 molar mixture of LiCl and InCl 3 via Bridgmantype crystal growth. The crystal structure (monoclinic, C2/m, Z = 2, a = 643.2(3), b = 1109.3(3), c = 639.8(3) pm, b = 109.8( 1)°R 1 = 0.0549, wR 2 = 0.1364 (all data) may be de-rived from the AlCl 3 -type of structure as was previously also found for the bromides Li 3 MBr 6 (M = Sm±Lu, Y) and iodides Li 3 MI 6 (M = Er±Yb, Y).