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Zur konfigurativen stabilität syn/anti-isomerer überbrückter [14]annulene mit anthracen-perimeter

✍ Scribed by E. Vogel; W. Tuckmantel; K. Schögl; M. Widhalm; E. Kraka; D. Cremer


Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
259 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis


The existence of a thermal equilibrium between aromatic syn-1,6:8,13-bisoxido[ 14lannulene and its olefinic anti-isomer is deduced from stereochemical and theoretical studies. Brucken-Inversionen sind einer der reizvollsten stereochemischen Aspekte syn/anti-isomerer Uberbrilckter [ 14lAnnulene mit Anthracen-Perimeter.Die Kohlenwasserstoffe syn-und anti-1,6:8,13-Bismethano[ 14]annulen [ (1)